橙皮素A的NMR研究

橙皮素A是从中药北沙参(Glehnia littoralis Fr. Schmidt ex Miquel)的正丁醇萃 取物中分离得到的一种8-O-4′-型异木脂素苷类化合物. 通过化学方法和波谱分析鉴 定了该 化合物的结构. 采用2D NMR技术对其NMR信号进行了全归属. DMSO-d₆代替CD₃OD作为溶剂，并利用重水交换，能准确读出偶合常数J_7,8值.      

Surface modifications of ITO electrodes for polymer light-emitting devices

Surface modifications were performed on the indium tin oxide (ITO) substrates for polymer light-emitting devices, using the different treatment methods including solvent cleaning, hydrochloric acid treatment and oxygen plasma. The influence of modifications on the surface properties of ITO electrodes were investigated by X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), contact angle, and four-point probe. The surface energies of the ITO substrates were also calculated from the measured contact angles. Experimental results demonstrate that the surface properties of the ITO substrates strongly depend on the modification methods, and oxygen plasma more effectively improves the ITO surface properties compared with the other treatments. Furthermore, the polymer light-emitting electrochemical cells (LECs) with the differently treated ITO substrates as device electrodes were fabricated and characterized. It is observed that the surface modifications on ITO electrodes have a certain degree of influence upon the injection current, luminance and efficiency, but hardly upon the turn-on voltages of current injection and light emission which are close to the measured energy gap of electroluminescent polymer. Oxygen plasma treatment on the ITO electrode yields the better performance of the LECs, due to the improvement of interface formation and electrical contact of the ITO electrode with the polymer blend in the LECs.     

Characteristics of soft magnetic composite material under rotating magnetic fluxes

This paper reports the measurement of magnetic properties of the soft magnetic composite material SOMALOY^TM 500 in a square sample under different patterns of flux density with 2D magnetic excitations. The test system, principle of measurement, magnetic power loss calculation, and methods of correction for misalignment of H surface sensing coils are presented. The experimental results show that although nominally isotropic, the SOMALOY^TM 500 sample exhibits some anisotropy. The results are useful in the design and performance analysis of rotating electrical machines.     

关于三次高斯和的均值

主要研究三次高斯和的均值性质，并给出一个较强的渐近公式。     

meso-四(4-乙酰氧基苯)卟啉-铜(Ⅱ)-乳化剂OP体系荧光熄灭法测定微量铜(Ⅱ)的研究

本文研究了高灵敏的meso-四(4-乙酰氧基苯)卟啉[T(4-AOP)P]-铜(Ⅱ-乳化剂OP体系。在酸度为pH5.0～5.6范围内形成的三元络合物可引起T(4-AOP)P-OP荧光强度的定量熄灭,其Ex=413nm,EM=656.9nm,Cu(Ⅱ)浓度在0～0.150μg/ml范围内有良好的线性关系,回归方程F=25.51-8.45m,试验了14种离子的干扰影响,并用此法测定了小球藻中Cu的含量,回收率达96～104％。     

北京自由电子激光最近进展──实现饱和振荡

北京自由电子激光(BFEL)装置于1993年底在10.68μm处实现了饱和振荡.输出激光能量为3mJ,饱和平顶宽度2μs.对应饱和振荡平均功率为210kW(宏脉冲),峰值功率约为20MW,比自发辐射高8个量级,单程小讯号净增益为24%,转换效率为0.45%,与理论预期结果相符.光束质量接近衍射极限.目前装置可工作于9-11μm.     

Theory on the optical-phonon Raman scattering in GaAs/AlAs heterostructures

A microscopic theory of Raman scattering by optical phonons in GaAs/GaAlAs heterostructures is worked out systematically, on the basis of recent advances in our knowledge of the electronic structure and the optical-phonon modes in superlattices and quantum wells. Theories have shown that specific features of the intermediate states are of special importance for a quantitative theory. Thus, the heavy and light hole mixing effect, and the angular momentum state of the four-component excitons, can play a decisive role in determining the predominant scattering channels. Special attention has been paid to the Frolich-interaction induced scattering, which is dipole forbidden in bulk materials but allowed in multiple quantum wells owing to the barrier penetration and the hole mixing. Based on the microscopic theory, explanations are provided for such experimental facts as the asymmetry between the incoming and the outgoing resonance, the line shape of Raman spectra and the features of two-phonon Raman scattering in quantum well systems.     

结构—饱和土壤相互作用的固结有限元分析

讨论了结构与饱和土壤相互作用的固结分析问题.对于结构利用多重子结构分析技术实现向饱和土交界面上的凝聚.从而建立了结构与饱和土壤相互作用的固结控制方程.文中给出了问题求解的一次性算法方案,采取压力主从关系的手段处理边界上的不排水条件.文末给出数值算例.本文工作为大型结构与土体相互作用固结分析研究工作的深入创造了条件.     

第二类Fredholm积分方程的泰勒展开解法

本进一步发展了用Taylor公式求解第二类Fredholm积分方程的方法，并给出了近似解的误差精度分析．     

应用美学原理进行愉悦式教学的尝试

由于物理学的学习难度均较大,使学生学习完全处于被动状态,如何扭转此局面呢?愉悦式教法定能如愿。1 让学生充分领略学科的美 要学好物理,首先必须对它们产生兴趣.学科安排本身就是一种美,加之论述的逻辑